Methyl Ethyl Ketone – removed from the list of hazardous air pollutants in December 2005 - Federal Register - December 19, 2005 (70 FR 75047). Alcohols exhibit both … May initiate the polymerization of isocyanates and epoxides. 3 Retain H302 H315 H319 Remove H312 Modify H331 Add GHS06 Dgr Remove GHS07 Wng Retain H302 H315 H319 Modify H331 Add inhalation: ATE = 3 mg/L oral: ATE = 1200 mg/kg bw Resulting Annex VI entry if agreed by COM For example KCN or Ca(CN)2, 2 - Includes mono- and di- ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n -OR' where Product Name Ethylene Glycol Monobutyl Ether (Laboratory) Cat No. Oxidizing agents convert alcohols to aldehydes or ketones. 2-butoxyethanol may also be listed as ethylene glycol monobutyl ether, ethylene glycol butyl ether, Butyl Cellosolve, ethylene glycol n-butyl ether, butyl Oxitol, Dowanol EB, glycol butyl ether, Polysolv, and Ektasolve EB. Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond. Alternative Name. To implement this action, EPA revised footnote 2 of the list (42 U.S.C. C 4 H 9 OCH 2 CH 2 OH. Agent Name. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Appearance. 12. NOTE: For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) 4 Skin Irrit. It is an odorless, colorless, sweet-tasting, viscous liquid. [7] Damit zählt es zu den chemischen Substanzen, die in großen Mengen hergestellt werden („High Production Volume Chemical“, HPVC) und für die von der Organisation für wirtschaftliche Zusammenarbeit und Entwicklung (OECD) eine Datensammlung zu möglichen Gefahren („Screening Information Dataset“, SIDS) angefertigt wurde. U.S. Environmental Protection Agency.                n = 1, 2, or 3 Ethylene glycol is chemically broken down in the body into toxic compounds. Flammability 1: Must be preheated before ignition can occur. DEGBE. Ethylene glycol is odorless; odor does not provide any warning of inhalation exposure to hazardous concentrations. [8], Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. It is an ether-ester derivative. Synonyms. Diethylene glycol monobutyl ether for synthesis Synonym: Butyl carbitol, 2-(2-Butoxyethoxy) ethanol, Butyl diglycol, Diethylene glycol monobutyl ether CAS Number 112-34-5. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). (1991) Definitive relationships among chemical structure, carcinogenicity and mutagenicity for 301 chemicals tested by the U.S. NTP. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016).                R' = H or alkyl C7 or less; or OR’ consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Linear Formula HOCH 2 CH 2 OCH 2 CH 2 O(CH 2) 3 CH 3. Under the Clean Air Act, EPA is required to regulate emissions of hazardous air pollutants. It is an ether-ester derivative. Ethylene glycol is chemically broken down in the body into toxic compounds. 2 BUTOXYETHANOL BUTYL GLYCOL ETHYLENE GLYCOL BUTYL ETHER Technical grade 2-Butoxyethanol is an organic solvent which is a clear, colourless liquid with an ether-like odour. Ethylene glycol is a “toxic alcohol”, meaning that although chemically it is similar to ethanol (the active component of alcoholic beverages), it is much more poisonous if consumed. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. CAS Number. Molecular Weight 162.23 . When aerosolized it acts as a disinfectant. Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. Colorless and clear liquid. On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. Synonym: 1-Acetoxy-2-ethoxyethane, Cellosolve ® acetate, Ethylene glycol monoethyl ether acetate Linear Formula: CH 3 COOCH 2 CH 2 OC 2 H 5 Molecular Weight: 132.16 " DISCLAIMER: The ILO does not take responsibility for content presented on this web portal that is presented in any language other than English, which is the language used for the initial production and peer-review of original content. Substance name : Glycol Ether EB CAS-No. [6], Die Jahresproduktion in Europa betrug 2003 etwa 161.000 Tonnen. Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. C 4 H 9 O(CH 2 CH 2 O) 3 H. C 4 H 9 O(CH 2 CH 2 O) n H, n=3-5. Return to footnote 13 referrer. EC … [9], Ethylenglycolmonobutylether wird als Lösungsmittel für Druckfarben, Verdünnungsmittel, Veredelungsmittel und zur Herstellung von Lacken verwendet. It has many names including ethylene glycol monobutyl ether, ethylene glycol butyl ether, ethylene glycol n-butyl ether, Butyl Cellusolve, butyl glycol, and butyl Oxitol. The relevance of this finding to humans is uncertain. C8-H18-O3. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. Surfactant alcohol ethoxylates and their derivatives - removed from the list of hazardous air pollutants in August 2000 - Federal Register – August 2, 2000 (65 FR 47342). Colorless liquid with a mild odor. 2-Butoxyethanol acetate Butyl Cellosolve acetate Butyl glycol acetate EGBEA Ektasolve EB acetate Ethylene glycol butyl ether acetate On November 29, 2004 (69FR69320) this proposal was made final. This document evaluates ethylene glycol (EG), diethylene glycol (DG), diethylene glycol monomethyl ether (DGME), diethylene glycol monoethyl ether (DGEE), and diethylene glycol monobutyl ether (DGBE), pesticide inert ingredients for which an exemption from the requirement of a tolerance exists. Januar 2021 um 17:42 Uhr bearbeitet. Toxicological Review of Ethylene Glycol Monobutyl Ether (EGBE) (CAS No. EPA/635/R-08/006F. It attacks some forms of plastics, rubber and … [7], Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. 13/606, Safepharm Laboratories, Ltd., Derby, U.K. Report to Mitsubishi Petrochemical Co., Ltd., Tokyo, Japan. 111-76-2) from the group of glycol ethers. They are alcoholic compounds due to the presence of –OH groups. 90-118. Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. 2 Remove Acute Tox. The acute and subehronic toxicity of EGEE, EGPE and EGBE was reviewed by C. C. Conaway (Texaco, Diamond Hazard Value Description; 1 1 0 Health 1: Can cause significant irritation. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten. Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. The ether being relatively unreactive. Ecological information ETHYLENE GLYCOL DIBUTYL ETHER may react violently with strong oxidizing agents. Diethylene glycol monobutyl ether. Hobson, D. W. et al (1986) A subchronic dermal exposure study of diethylene glycol monomethyl ether and ethylene glycol monomethyl ether in the male guinea pig. ethylene glycol monobutyl ether (butyl cellosolve) 2909.43.00 101 Ethers, ether-alcohols, ether-phenols, ether-alcohol-phenols, alcohol peroxides, ether peroxides, ketone peroxides (whether or not chemically defined), and their halogenated, sulphonated, nitrated or nitrosated derivatives. Diethylene glycol ethers were absorbed more slowly than the corresponding ethylene glycol ethers. 7412(b)(1). 5 - A type of atom which spontaneously undergoes radioactive decay. Workers may be harmed from exposure to 2-butoxyethanol. 7412(b)(1)) to read as follows: 2 - Includes mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR' , where: Impurities. In rats, deaths in response to single oral exposures are attributable to narcosis, whereas delayed deaths result from lung congestion and renal failure. On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. Solvents. United States Environmental Protection Agency, removed from the list of hazardous air pollutants in December 2005, removed from the list of hazardous air pollutants (glycol ethers category) in November 2004, removed from the list of hazardous air pollutants in June 1996, removed from the list of hazardous air pollutants in August 2000, Benzene (including benzene from gasoline), Cresols/Cresylic acid (isomers and mixture), Dichloroethyl ether (Bis(2-chloroethyl)ether), Epichlorohydrin (l-Chloro-2,3-epoxypropane), Ethylidene dichloride (1,1-Dichloroethane), Methyl chloroform (1,1,1-Trichloroethane), Propylene dichloride (1,2-Dichloropropane), Vinylidene chloride (1,1-Dichloroethylene), Arsenic Compounds (inorganic including arsine). Production Industrial routes. Hydrogen Sulfide – added to the list inadvertently but removed by Congress with Presidential approval in 1991. Fundamental & Applied Toxicology 6:2:339-348.                n = 1, 2, or 3; Ethylene glycol monobutyl ether: Toxic effects include lethargy, coma, anion gap metabolic acidosis, hyperchloremia, hypotension, respiratory depression, hemolysis, renal and hepatic dysfunction. Ethylene glycol is odorless; odor does not provide any warning of … Agent Name. 111-76-2. Propylene Glycol: Propylene Glycol is used as a solvent for intravenous, oral, and topical pharmaceutical preparations. 2. List of Hazardous Air Pollutants, Petition Process, Lesser Quantity Designations, Source Category List; Petition To Delist of Ethylene Glycol Monobutyl Ether . Alcohols exhibit both … Buy Glycol Ether For $35 | Buy In Bulk Online For $60 | Butyl Cellosolve | Solvent, Coupling Agent & Cleaner | Formula C6H14O2 | Glycol Ether EB SDS | CAS # 111-76-2 | Ethylene Glycol Monobutyl Ether | 2-Butoxyethanol | Ethylene Glycol Monobutyl Ether Acetate | Butoxyethyl Acetate | Butyl Glycol Acetate | Ethylene Glycol Butyl Ether Acetate Ethylene glycol monobutyl ether has been shown to cause cancer in laboratory animals. : E181-4 Synonyms Oxitol acetate; 2-Ethoxyethyl acetate; Cellosolve acetate Recommended Use Laboratory chemicals. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH 2 OH) 2. Major Category. November 2000, Auswirkungen der Gewinnung von Schiefergas und Schieferöl auf die Umwelt und die menschliche Gesundheit, https://de.wikipedia.org/w/index.php?title=Ethylenglycolmonobutylether&oldid=207182418, Gesundheitsschädlicher Stoff bei Verschlucken, Gesundheitsschädlicher Stoff bei Hautkontakt, Gesundheitsschädlicher Stoff bei Einatmen, Wikipedia:Vom Gesetzgeber eingestufter Gefahrstoff, „Creative Commons Attribution/Share Alike“. Alternative Name. The level of exposure depends upon the dose, duration, and work being done. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. Diethylene glycol (DEG) is a clear, colorless, odorless liquid with a sweet taste, and is an excellent solvent for water-insoluble chemicals and drugs. Etwa 60 % der Verbindung wird in Europa für Farben und Lacken verwendet, etwa 11 % wird in Wasch- und Reinigungsmitteln verwendet und bis zu 0,5 % wird als Lösungsmittel in Haarfärbemitteln benutzt. ACTION: Final rule. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. 2010. It is used as a plasticizer for vinyl polymers.It is also used in air sanitizer products, such as "Oust" or "Clean and Pure". They react with oxoacids and carboxylic acids to form esters plus water. Rats and mice chronically (long-term) exposed to ethylene glycol in their diet exhibited signs of kidney toxicity and liver effects. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). The acetate form of 2-butoxyethanol may be listed as Ethylene glycol monobutyl ether for synthesis. (1993d) Ethylene glycol monobutyl ether: acute dermal toxicity test in the rabbit. The ether being relatively unreactive. 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. [6], Ethylenglycolmonobutylether ist eine farblose Flüssigkeit mit schwach etherischem Geruch. Since 1990, EPA has modified the list through rulemaking to include 187 hazardous air pollutants. 1 - X'CN where X = H' or any other group where a formal dissociation may occur. Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 OH. In both the ethylene and diethylene glycol series, the relative rate of absorption declined from methyl to ethyl to butyl ether derivatives. Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) ... is produced by the reaction of ethylene oxide and n-butanol with an alkalic catalyst. [9] 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. Formula. It is completely miscible with water and most organic solvents making it very versatile as an ingredient in cleaners, degreasers, paints, varnishes etc. Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. MDL number MFCD00002881. Ashby, J; Tennant, RW. Ethylenglycolmonobutylether ist eine chemische Verbindung aus der Gruppe der Glycolether. 143-22-6. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). 2. , except CAS #111-76-2, ethylene glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol. C 4 H 9 OCH 2 CH 2 OCH 2 CH 2 OH. [8] Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. 2 Eye Irrit. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Ethylene Glycol 107-21-1 Hazard Summary Ethylene glycol has many uses, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and as a solvent. Considerable potassium efflux, protein leakage, and inhibition of endogenous respiration were observed in the presence of the more toxic compounds. Instability 0: Normally stable, even under fire conditions. 2-BE itself is not commercially produced in Canada.                R = alkyl or aryl groups 2-Butoxyethanol is a clear colorless liquid that smells like ether. 2-Butoxyethanol is an organic compound with the chemical formula BuOC 2 H 4 OH (Bu = CH 3 CH 2 CH 2 CH 2).This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol.As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. Ethylene glycol has a sweet taste and is often accidentally or intentionally ingested. Maternally toxic dose levels of ethylene glycol monobutyl ether and ethanol were associated with increased embryo lethality in teratology probe studies. AGENCY: Environmental Protection Agency (EPA). They react with oxoacids and carboxylic acids to form esters plus water. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. 3 - Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less. Beim Menschen wurde nach oraler Exposition mit etwa 0,5 und 1,5 g/kg Körpergewicht und anfänglich schweren Symptomen eine vollständige Erholung beobachtet.[7].
Zeebrugge Raid Medals, Eagle Pass Tx Connect, Within A Tight Deadline, Interpretation Of Psalm 133, Mark Love Island, Cheap Apartments In London, Valet Living Pay Schedule, Maroon 5 This Love, Ashok Dinda Cricbuzz Profile, Sino Ang Diyosa Ng Kaluluwa,